Literature DB >> 24419329

Ligand-free hydroboration of alkynes catalyzed by heterogeneous copper powder with high efficiency.

Jie Zhao1, Zhiqiang Niu, Hua Fu, Yadong Li.   

Abstract

Regioselective hydroboration of terminal and internal alkynes is realized by using 10 mol% copper powder (0.3-1 μm) at room temperature. 24 alkynes were efficiently converted into vinylboronates in up to 96% yield without addition of any ligand or additive.

Entities:  

Year:  2014        PMID: 24419329     DOI: 10.1039/c3cc48670b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  5 in total

1.  Design and development of FGF-23 antagonists: Definition of the pharmacophore and initial structure-activity relationships probed by synthetic analogues.

Authors:  Ryan P Downs; Zhousheng Xiao; Munachi O Ikedionwu; Jacob W Cleveland; Ai Lin Chin; Abigail E Cafferty; L Darryl Quarles; Jesse D Carrick
Journal:  Bioorg Med Chem       Date:  2020-11-18       Impact factor: 3.641

2.  Total Synthesis of the Spliceosome Modulator Pladienolide B via Asymmetric Alcohol-Mediated syn- and anti-Diastereoselective Carbonyl Crotylation.

Authors:  Minjin Yoo; Michael J Krische
Journal:  Angew Chem Int Ed Engl       Date:  2021-05-11       Impact factor: 16.823

Review 3.  Total Syntheses of Pladienolide-Derived Spliceosome Modulators.

Authors:  Jaehoon Sim; Eunbin Jang; Hyun Jin Kim; Hongjun Jeon
Journal:  Molecules       Date:  2021-09-30       Impact factor: 4.411

4.  A simple synthesis of surfactant-free polycrystalline CuO nanoparticles supported on carbon nanofibers for regioselective hydroboration of alkynes.

Authors:  Balaji Mohan; Kyung Hee Oh; Ji Chan Park; Mohammad Yusuf; Kang Hyun Park; Buhyun Youn
Journal:  RSC Adv       Date:  2022-09-01       Impact factor: 4.036

5.  Ru-catalyzed isomerization of ω-alkenylboronates towards stereoselective synthesis of vinylboronates with subsequent in situ functionalization.

Authors:  Guo-Ming Ho; Lucas Segura; Ilan Marek
Journal:  Chem Sci       Date:  2020-05-26       Impact factor: 9.825

  5 in total

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