| Literature DB >> 24419097 |
Javier Ruiz1, Lucía García, Carmen Mejuto, Marilín Vivanco, M Rosario Díaz, Santiago García-Granda.
Abstract
By choosing the appropriate coupling reactions an isocyanide ligand in complex [Fe(Cp)(CO)(CNxylyl)2](+) is transformed into either a conventional NHC or into a metalla-N-heterocyclic carbene (MNHC), with the stretching frequencies of the CO and CNR ligands attached to the iron center demonstrating the stronger electron-donating ability of the metal-containing carbenes.Entities:
Year: 2014 PMID： 24419097 DOI： 10.1039/c3cc47987k
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222