| Literature DB >> 24413586 |
Zi-Yi Du1, Ying-Ping Zhao, Wei-Xiong Zhang, Hao-Long Zhou, Chun-Ting He, Wei Xue, Bao-Ying Wang, Xiao-Ming Chen.
Abstract
A new perovskite-like compound [N(CH3)4][Cd(N3)3] is reported here, which undergoes a series of reversible phase transitions including an above-room-temperature ferroelastic phase transition. An order-disorder mechanism is found in these structural transitions owing to the sway of the rod-like N3(-) bridges as well as the rotation of the tetrahedron-like [N(CH3)4](+) guests.Entities:
Year: 2014 PMID: 24413586 DOI: 10.1039/c3cc48581a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222