Literature DB >> 24409458

Ethene/alkyne exchange reaction at an intramolecular frustrated Lewis pair.

Christina Eller1, Kathrin Bussmann, Gerald Kehr, Birgit Wibbeling, Constantin G Daniliuc, Gerhard Erker.   

Abstract

A vicinal ethylene bridged S/B frustrated Lewis pair (FLP) in situ generated by a hydroboration reaction of phenyl vinyl sulfide, reacts with p-tert-butylphenylacetylene by ethene/alkyne exchange and subsequent 1,2-addition of a second alkyne equivalent to give a zwitterionic sulfonium/borate product.

Entities:  

Year:  2014        PMID: 24409458     DOI: 10.1039/c3cc47769j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Advanced 1,1-carboboration reactions with pentafluorophenylboranes.

Authors:  Gerald Kehr; Gerhard Erker
Journal:  Chem Sci       Date:  2015-10-08       Impact factor: 9.825

  1 in total

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