| Literature DB >> 24394960 |
Atsutoshi Yokoyama1, Jung Eun Han, Kenneth D Karlin, Wonwoo Nam.
Abstract
Reaction of a nonheme iron(III)-peroxo complex, [Fe(III)(14-TMC)(O2)](+), with NO(+), a transformation which is essentially isoelectronic with that for nitric oxide dioxygenases [Fe(III)(O2˙(-)) + NO], affords an iron(IV)-oxo complex, [Fe(IV)(14-TMC)(O)](2+), and nitrogen dioxide (NO2), followed by conversion to an iron(III)-nitrato complex, [Fe(III)(14-TMC)(NO3)(F)](+).Entities:
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Year: 2014 PMID: 24394960 PMCID: PMC4078658 DOI: 10.1039/c3cc48782b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222