Literature DB >> 24383448

The elusive three-coordinate dicationic hydrido boron complex.

Wen-Ching Chen1, Ching-Yu Lee, Bo-Chao Lin, Yu-Chen Hsu, Jiun-Shian Shen, Chao-Ping Hsu, Glenn P A Yap, Tiow-Gan Ong.   

Abstract

The formation of a hitherto unknown three-coordinate dicationic hydrido boron complex is described. Interestingly, supporting ligand carbodicarbene gave unprecedented reaction with BH3 without using more highly electrophilic Lewis acid precursors. Spectroscopic, crystallographic, and computational analysis was performed to understand the electronic features of these species.

Entities:  

Year:  2014        PMID： 24383448     DOI： 10.1021/ja4120852

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  5 in total

1.  Carbodiphosphorane mediated synthesis of a triflyloxyphosphonium dication and its reactivity towards nucleophiles.

Authors:  S Yogendra; F Hennersdorf; A Bauzá; A Frontera; R Fischer; J J Weigand
Journal:  Chem Commun (Camb)       Date:  2017-03-07       Impact factor: 6.222

2.  Using Ylide Functionalization to Stabilize Boron Cations.

Authors:  Thorsten Scherpf; Kai-Stephan Feichtner; Viktoria H Gessner
Journal:  Angew Chem Int Ed Engl       Date:  2017-02-10       Impact factor: 15.336

3.  Cationic Phosphorus Compounds Based on a Bis(1-piperidinyl)-Substituted Carbodiphosphorane: Syntheses, Structures, and Csp3 -H Activation.

Authors:  Alexander Kroll; Henning Steinert; Mike Jörges; Tim Steinke; Bert Mallick; Viktoria H Gessner
Journal:  Organometallics       Date:  2020-08-26       Impact factor: 3.876

4.  A crystalline radical cation derived from Thiele's hydrocarbon with redox range beyond 1 V.

Authors:  Ying Kai Loh; Petra Vasko; Caitilín McManus; Andreas Heilmann; William K Myers; Simon Aldridge
Journal:  Nat Commun       Date:  2021-12-03       Impact factor: 14.919

5.  Unraveling the reactivity of a cationic iminoborane: avenues to unusual boron cations.

Authors:  Rui Guo; Xin Zhang; Tong Li; Qianli Li; David A Ruiz; Liu Leo Liu; Chen-Ho Tung; Lingbing Kong
Journal:  Chem Sci       Date:  2022-01-26       Impact factor: 9.825
  5 in total

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