Literature DB >> 24380447

Synthesis and single crystal structure of sodium octahydrotriborate, NaB3H8.

Andrew C Dunbar1, Joseph A Macor, Gregory S Girolami.   

Abstract

This paper describes a modified synthesis of NaB3H8 by the reduction of BH3·THF with sodium dispersed on silica gel. Single crystals obtained from CH2Cl2 show conclusively that the space group is Pmn21, in contrast to the Pmmn space group previously deduced from powder diffraction data.

Entities:  

Year:  2013        PMID: 24380447     DOI: 10.1021/ic402127x

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  2 in total

1.  [(Cp2M)2B9H11] (M = Zr or Hf): early transition metal 'guarded' heptaborane with strong covalent and electrostatic bonding.

Authors:  Anangsha De; Qian-Fan Zhang; Bijan Mondal; Ling Fung Cheung; Sourav Kar; Koushik Saha; Babu Varghese; Lai-Sheng Wang; Sundargopal Ghosh
Journal:  Chem Sci       Date:  2018-01-11       Impact factor: 9.825

Review 2.  Polyhedral [M2B5] Metallaborane Clusters and Derivatives: An Overview of Their Structural Features and Chemical Bonding.

Authors:  Rini Prakash; Jean-François Halet; Sundargopal Ghosh
Journal:  Molecules       Date:  2020-07-12       Impact factor: 4.411

  2 in total

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