Literature DB >> 24377744

Synthesis and characterization of [Ru@Ge12]3-: an endohedral 3-connected cluster.

Gabriela Espinoza-Quintero1, Jack C A Duckworth, William K Myers, John E McGrady, Jose M Goicoechea.   

Abstract

The 12-vertex endohedral cluster [Ru@Ge12](3-) reveals an unprecedented D2d-symmetric 3-connected polyhedral geometry. The structure contrasts dramatically with the known deltahedral or approximately deltahedral geometries of [M@Pb12](2-) (M = Ni, Pd, Pt) and [Mn@Pb12](3-) and is a result of extensive delocalization of electron density from the transition-metal center onto the cage.

Entities:  

Year:  2014        PMID： 24377744     DOI： 10.1021/ja411280v

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  4 in total

1.  Probing the structural evolution of ruthenium doped germanium clusters: Photoelectron spectroscopy and density functional theory calculations.

Authors:  Yuanyuan Jin; Shengjie Lu; Andreas Hermann; Xiaoyu Kuang; Chuanzhao Zhang; Cheng Lu; Hongguang Xu; Weijun Zheng
Journal:  Sci Rep       Date:  2016-07-21       Impact factor: 4.379

2.  Metallocages for Metal Anions: Highly Charged [Co@Ge9 ]5- and [Ru@Sn9 ]6- Clusters Featuring Spherically Encapsulated Co1- and Ru2- Anions.

Authors:  Benedikt J L Witzel; Wilhelm Klein; Jasmin V Dums; Marina Boyko; Thomas F Fässler
Journal:  Angew Chem Int Ed Engl       Date:  2019-08-21       Impact factor: 15.336

3.  Understanding of multimetallic cluster growth.

Authors:  Stefan Mitzinger; Lies Broeckaert; Werner Massa; Florian Weigend; Stefanie Dehnen
Journal:  Nat Commun       Date:  2016-01-25       Impact factor: 14.919

4.  Synthesis and structure of a family of rhodium polystannide clusters [Rh@Sn10]3-, [Rh@Sn12]3-, [Rh2@Sn17]6- and the first triply-fused stannide, [Rh3@Sn24]5.

Authors:  Chao Liu; Xiao Jin; Lei-Jiao Li; Jun Xu; John E McGrady; Zhong-Ming Sun
Journal:  Chem Sci       Date:  2019-03-11       Impact factor: 9.825
  4 in total

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