Josef Havel1, Eladia Maria Peña-Méndez, Filippo Amato, Nagender Reddy Panyala, Vilma Buršíková. 1. Department of Chemistry, Faculty of Science, Masaryk University, Kampus Bohunice, Kamenice 5/A14, 625 00, Brno, Czech Republic; Department of Physical Electronics, Faculty of Science, Masaryk University, Kotlářská 2, 611 37, Brno, Czech Republic; CEPLANT, R&D Centre for Low-cost Plasma and Nanotechnology Surface Modifications, Masaryk University, Kotlářská 2, 611 37, Brno, Czech Republic.
Abstract
RATIONALE: Gold carbides can be produced via laser ablation synthesis (LAS) from mixtures of nano-gold (NG) and various carbonaceous materials. The nano-composite of nano-gold (NG) and nano-diamond (ND) might represent a promising precursor for the generation of new gold carbides. METHODS: Time-of-flight mass spectrometry (TOF MS), transmission electron microscopy (TEM) and energy-dispersive X-ray spectroscopy (EDX) were used. The stoichiometry of clusters was determined via modelling of the isotopic patterns and MS(n) analysis. RESULTS: A simple procedure for the preparation of ND-NG nano-composite was developed using NG and ND. The formation of AuCn(+) (n = 1-11, 18), Au2Cn(+) (n = 1-16) and Au3Cn(+) (n = 1-10) clusters during LAS of the nano-composite was proved. Structures of gold carbides are proposed and discussed. Diamonds-containing AumCn(+) (m = 1-3, n = 10, 14, 18, 22) clusters might be not carbides but endohedral supramolecular complexes Aum@Cn(+) i.e., 'gold-doped' diamonds. CONCLUSIONS: TOF MS was shown to be a useful technique for following the formation of gold carbides in the gas phase. Clusters and 'gold-doped' diamonds generated might inspire synthesis of new Au-C materials with hardly predictable, unusual properties.
RATIONALE: Gold carbides can be produced via laser ablation synthesis (LAS) from mixtures of nano-gold (NG) and various carbonaceous materials. The nano-composite of nano-gold (NG) and nano-diamond (ND) might represent a promising precursor for the generation of new gold carbides. METHODS: Time-of-flight mass spectrometry (TOF MS), transmission electron microscopy (TEM) and energy-dispersive X-ray spectroscopy (EDX) were used. The stoichiometry of clusters was determined via modelling of the isotopic patterns and MS(n) analysis. RESULTS: A simple procedure for the preparation of ND-NG nano-composite was developed using NG and ND. The formation of AuCn(+) (n = 1-11, 18), Au2Cn(+) (n = 1-16) and Au3Cn(+) (n = 1-10) clusters during LAS of the nano-composite was proved. Structures of gold carbides are proposed and discussed. Diamonds-containing AumCn(+) (m = 1-3, n = 10, 14, 18, 22) clusters might be not carbides but endohedral supramolecular complexes Aum@Cn(+) i.e., 'gold-doped' diamonds. CONCLUSIONS: TOF MS was shown to be a useful technique for following the formation of gold carbides in the gas phase. Clusters and 'gold-doped' diamonds generated might inspire synthesis of new Au-C materials with hardly predictable, unusual properties.