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Literature DB >> 24366363

Structural and magnetic conformation of a cerocene [Ce(COT'')2]- exhibiting a uniconfigurational f1 ground state and slow-magnetic relaxation.

Jennifer J Le Roy¹, Ilia Korobkov, Jee Eon Kim, Eric J Schelter, Muralee Murugesu.

Abstract

Magnet-like behaviour, in the form of slow relaxation of the magnetization, was observed for a monometallic cerium(III) sandwich complex. The use of trimethylsilyl substituted COT ligands (COT'') led to the formation of a staggered COT'' arrangement in the cerocene-type sandwich complex with a well-defined oxidation state of +3 for the Ce ion.

Entities: Chemical

Year: 2014 PMID： 24366363 DOI： 10.1039/c3dt53280a

Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390

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Cited

7 in total

1. Magnetic anisotropy of endohedral lanthanide ions: paramagnetic NMR study of MSc₂N@C₈₀-I_h with M running through the whole 4f row.

Authors: Y Zhang; D Krylov; M Rosenkranz; S Schiemenz; A A Popov
Journal: Chem Sci Date: 2015-01-28 Impact factor: 9.825

2. Chemical tunnel-splitting-engineering in a dysprosium-based molecular nanomagnet.

Authors: Mikkel A Sørensen; Ursula B Hansen; Mauro Perfetti; Kasper S Pedersen; Elena Bartolomé; Giovanna G Simeoni; Hannu Mutka; Stéphane Rols; Minki Jeong; Ivica Zivkovic; Maria Retuerto; Ana Arauzo; Juan Bartolomé; Stergios Piligkos; Høgni Weihe; Linda H Doerrer; Joris van Slageren; Henrik M Rønnow; Kim Lefmann; Jesper Bendix
Journal: Nat Commun Date: 2018-03-29 Impact factor: 14.919

3. Synthesis, structures and magnetic properties of [(η⁹-C₉H₉)Ln(η⁸-C₈H₈)] super sandwich complexes.

Authors: L Münzfeld; C Schoo; S Bestgen; E Moreno-Pineda; R Köppe; M Ruben; P W Roesky
Journal: Nat Commun Date: 2019-07-17 Impact factor: 14.919

4. Importance of an Axial Ln^III-F Bond across the Lanthanide Series and Single-Molecule Magnet Behavior in the Ce and Nd Analogues.

Authors: Emma Regincós Martí; Angelos B Canaj; Tanu Sharma; Anna Celmina; Claire Wilson; Gopalan Rajaraman; Mark Murrie
Journal: Inorg Chem Date: 2022-06-21 Impact factor: 5.436

Structural and magnetic conformation of a cerocene [Ce(COT'')2]- exhibiting a uniconfigurational f1 ground state and slow-magnetic relaxation.

1. Magnetic anisotropy of endohedral lanthanide ions: paramagnetic NMR study of MSc₂N@C₈₀-I_h with M running through the whole 4f row.

2. Chemical tunnel-splitting-engineering in a dysprosium-based molecular nanomagnet.

3. Synthesis, structures and magnetic properties of [(η⁹-C₉H₉)Ln(η⁸-C₈H₈)] super sandwich complexes.

4. Importance of an Axial Ln^III-F Bond across the Lanthanide Series and Single-Molecule Magnet Behavior in the Ce and Nd Analogues.

5. Insights into the Spin Dynamics of Mononuclear Cerium(III) Single-Molecule Magnets.

6. A Low Spin Manganese(IV) Nitride Single Molecule Magnet.

7. Single-Ion Anisotropy and Intramolecular Interactions in Ce^III and Nd^III Dimers.