Literature DB >> 24359111

Huge magnetic anisotropy in a trigonal-pyramidal nickel(II) complex.

Silvia Gómez-Coca1, Eduard Cremades, Núria Aliaga-Alcalde, Eliseo Ruiz.   

Abstract

The work presented herein shows the experimental and theoretical studies of a mononuclear nickel(II) complex with the largest magnetic anisotropy ever reported. The zero-field-splitting D parameter, extracted from the fits of the magnetization and susceptibility measurements, shows a large value of -200 cm(-1), in agreement with the theoretical value of -244 cm(-1) obtained with the CASPT2-RASSI method.

Entities:  

Year:  2013        PMID： 24359111     DOI： 10.1021/ic402256v

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  2 in total

1.  Ligand design of zero-field splitting in trigonal prismatic Ni(II) cage complexes.

Authors:  Anthony J Campanella; Tyler M Ozvat; Joseph M Zadrozny
Journal:  Dalton Trans       Date:  2022-02-22       Impact factor: 4.390

2.  Generation of a Hetero Spin Complex from Iron(II) Iodide with Redox Active Acenaphthene-1,2-Diimine.

Authors:  Dmitriy S Yambulatov; Stanislav A Nikolaevskii; Mikhail A Kiskin; Kirill V Kholin; Mikhail N Khrizanforov; Yulia G Budnikova; Konstantin A Babeshkin; Nikolay N Efimov; Alexander S Goloveshkin; Vladimir K Imshennik; Yurii V Maksimov; Evgeny M Kadilenko; Nina P Gritsan; Igor L Eremenko
Journal:  Molecules       Date:  2021-05-18       Impact factor: 4.411
  2 in total

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