Literature DB >> 24343416

Stabilisation of μ-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands.

József S Pap1, Apparao Draksharapu, Michel Giorgi, Wesley R Browne, József Kaizer, Gábor Speier.   

Abstract

The spectroscopic characterisation of the (μ-1,2-peroxido)diiron(iii) species formed transiently upon reaction of [Fe(ii)(NN)3](2+) complexes with H2O2 by UV/vis absorption and resonance Raman spectroscopy is reported. The intermediacy of such species in the disproportionation of H2O2 is demonstrated.

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Year:  2014        PMID： 24343416     DOI： 10.1039/c3cc48196d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

Review 1.  Dioxygen Activation by Nonheme Diiron Enzymes: Diverse Dioxygen Adducts, High-Valent Intermediates, and Related Model Complexes.

Authors:  Andrew J Jasniewski; Lawrence Que
Journal:  Chem Rev       Date:  2018-02-05       Impact factor: 60.622

2.  Sc3+-Promoted O-O Bond Cleavage of a (μ-1,2-Peroxo)diiron(III) Species Formed from an Iron(II) Precursor and O2 to Generate a Complex with an FeIV2(μ-O)2 Core.

Authors:  Saikat Banerjee; Apparao Draksharapu; Patrick M Crossland; Ruixi Fan; Yisong Guo; Marcel Swart; Lawrence Que
Journal:  J Am Chem Soc       Date:  2020-02-19       Impact factor: 15.419

3.  Catalytic and Stoichiometric Baeyer-Villiger Oxidation Mediated by Nonheme Peroxo-Diiron(III), Acylperoxo, and Iodosylbenzene Iron(III) Intermediates.

Authors:  Dóra Lakk-Bogáth; Miklós István Szávuly; Patrik Török; József Kaizer
Journal:  Molecules       Date:  2022-04-28       Impact factor: 4.927

4.  A novel coordination mode of κ1-N-Br-pyridylbenz-(imida, oxa or othia)-zole to Pt(ii): synthesis, characterization, electrochemical and structural analysis.

Authors:  Juan Nicasio-Collazo; Gonzalo Ramírez-García; Marcos Flores-Álamo; Silvia Gutiérrez-Granados; Juan M Peralta-Hernández; José Luis Maldonado; J Oscar C Jimenez-Halla; Oracio Serrano
Journal:  RSC Adv       Date:  2019-05-07       Impact factor: 4.036
  4 in total

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