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Literature DB >> 24339396

Selective hydrogen production from methanol with a defined iron pincer catalyst under mild conditions.

Elisabetta Alberico¹, Peter Sponholz, Christoph Cordes, Martin Nielsen, Hans-Joachim Drexler, Wolfgang Baumann, Henrik Junge, Matthias Beller.

Abstract

Molecularly well-defined iron pincer complexes promote the aqueous-phase reforming of methanol to carbon dioxide and hydrogen, which is of interest in the context of a methanol and hydrogen economy. For the first time, the use of earth-abundant iron complexes under mild conditions for efficient hydrogen generation from alcohols is demonstrated.

Entities: Chemical

Keywords: homogeneous catalysis; hydrogen; iron catalysts; methanol; renewable energy

Mesh：

Substances：
Hydrogen
Iron
Methanol

Year: 2013 PMID： 24339396 DOI： 10.1002/anie.201307224

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

22 in total

1. Reversible catalytic dehydrogenation of alcohols for energy storage.

Authors: Peter J Bonitatibus; Sumit Chakraborty; Mark D Doherty; Oltea Siclovan; William D Jones; Grigorii L Soloveichik
Journal: Proc Natl Acad Sci U S A Date: 2015-01-14 Impact factor: 11.205

2. Ruthenium (II) and Iridium (III) Complexes of N-Heterocyclic Carbene and Pyridinol Derived Bidentate Chelates: Synthesis, Characterization, and Reactivity.

Authors: Deidra L Gerlach; Sopheavy Siek; Dalton B Burks; Jamie M Tesh; Courtney R Thompson; Robert M Vasquez; Nicholas J White; Matthias Zeller; Douglas B Grotjahn; Elizabeth T Papish
Journal: Inorganica Chim Acta Date: 2017-07-01 Impact factor: 2.545

3. Enthalpy-Controlled Insertion of a "Nonspectator" Tricoordinate Phosphorus Ligand into Group 10 Transition Metal-Carbon Bonds.

Authors: Seung Jun Hwang; Akira Tanushi; Alexander T Radosevich
Journal: J Am Chem Soc Date: 2020-12-11 Impact factor: 15.419

Review 4. Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics.

Authors: Amit Kumar; Prosenjit Daw; David Milstein
Journal: Chem Rev Date: 2021-11-02 Impact factor: 60.622

Selective hydrogen production from methanol with a defined iron pincer catalyst under mild conditions.

1. Reversible catalytic dehydrogenation of alcohols for energy storage.

2. Ruthenium (II) and Iridium (III) Complexes of N-Heterocyclic Carbene and Pyridinol Derived Bidentate Chelates: Synthesis, Characterization, and Reactivity.

3. Enthalpy-Controlled Insertion of a "Nonspectator" Tricoordinate Phosphorus Ligand into Group 10 Transition Metal-Carbon Bonds.

Review 4. Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics.

5. Tetrairon(II) extended metal atom chains as single-molecule magnets.

6. Tuning Ruthenium Carbene Complexes for Selective P-H Activation through Metal-Ligand Cooperation.

7. Acceptorless Dehydrogenation of Methanol to Carbon Monoxide and Hydrogen using Molecular Catalysts.

8. A novel liquid organic hydrogen carrier system based on catalytic peptide formation and hydrogenation.

9. Reactivity of a Ruthenium-Carbonyl Complex in the Methanol Dehydrogenation Reaction.

10. Dehydrogenation of anhydrous methanol at room temperature by o-aminophenol-based photocatalysts.