Literature DB >> 24328422

Iodine-catalyzed regioselective 2-sulfonylation of indoles with sodium sulfinates.

Fuhong Xiao1, Hui Chen, Hao Xie, Shuqing Chen, Luo Yang, Guo-Jun Deng.   

Abstract

Iodine-catalyzed selective 2-arylsulfonyl indole formation from indoles and sodium sulfinates is disclosed. Various substituted 2-arylsulfonyl indoles were obtained in one pot in the absence of metal catalyst at room temperature under air.

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Year:  2013        PMID： 24328422     DOI： 10.1021/ol402987u

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  8 in total

1.  A new cascade halosulfonylation of 1,7-enynes toward 3,4-dihydroquinolin-2(1H)-ones via sulfonyl radical-triggered addition/6-exo-dig cyclization.

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Journal:  Chem Commun (Camb)       Date:  2016-01-31       Impact factor: 6.222

Review 2.  Synthesis and applications of sodium sulfinates (RSO2Na): a powerful building block for the synthesis of organosulfur compounds.

Authors:  Raju Jannapu Reddy; Arram Haritha Kumari
Journal:  RSC Adv       Date:  2021-03-01       Impact factor: 3.361

Review 3.  Recent Progress and Emerging Technologies towards a Sustainable Synthesis of Sulfones.

Authors:  Shuai Liang; Kamil Hofman; Marius Friedrich; Julian Keller; Georg Manolikakes
Journal:  ChemSusChem       Date:  2021-10-13       Impact factor: 9.140

4.  Alkyl Sulfinates: Formal Nucleophiles for Synthesizing TosMIC Analogs.

Authors:  J Armando Lujan-Montelongo; Angel Ojeda Estevez; Fraser F Fleming
Journal:  European J Org Chem       Date:  2015-03

5.  The fast and efficient KI/H2O2 mediated 2-sulfonylation of indoles and N-methylpyrrole in water.

Authors:  Jun Zhang; Zhong Wang; Lingjuan Chen; Yan Liu; Ping Liu; Bin Dai
Journal:  RSC Adv       Date:  2018-12-12       Impact factor: 4.036

6.  Direct sulfonylation of anilines mediated by visible light.

Authors:  Tarn C Johnson; Bryony L Elbert; Alistair J M Farley; Timothy W Gorman; Christophe Genicot; Bénédicte Lallemand; Patrick Pasau; Jakub Flasz; José L Castro; Malcolm MacCoss; Darren J Dixon; Robert S Paton; Christopher J Schofield; Martin D Smith; Michael C Willis
Journal:  Chem Sci       Date:  2017-11-16       Impact factor: 9.825

7.  Regioselective C-H sulfenylation of N-sulfonyl protected 7-azaindoles promoted by TBAI: a rapid synthesis of 3-thio-7-azaindoles.

Authors:  Jingyan Hu; Xiaoming Ji; Shuai Hao; Mingqin Zhao; Miao Lai; Tianbao Ren; Gaolei Xi; Erbin Wang; Juanjuan Wang; Zhiyong Wu
Journal:  RSC Adv       Date:  2020-08-27       Impact factor: 4.036

8.  Homocouplings of Sodium Arenesulfinates: Selective Access to Symmetric Diaryl Sulfides and Diaryl Disulfides.

Authors:  Xin-Zhang Yu; Wen-Long Wei; Yu-Lan Niu; Xing Li; Ming Wang; Wen-Chao Gao
Journal:  Molecules       Date:  2022-09-22       Impact factor: 4.927
  8 in total

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