Literature DB >> 24313897

Tetrafluorothiophene S,S-dioxide: a perfluorinated building block.

David M Lemal1, Marc Akashi, Yan Lou, Vivek Kumar.   

Abstract

Tetrafluorothiophene S,S-dioxide, a highly reactive diene and dienophile, has been synthesized. A new route to 3,4-difluoro- and tetrafluorothiophene has been realized, and the previously unknown 2,3,4-trifluorothiophene has been obtained. The reactivity of tetrafluorothiophene S-oxide has been compared with that of the S,S-dioxide.

Entities:  

Year:  2013        PMID: 24313897     DOI: 10.1021/jo402373x

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  2 in total

1.  Origin of π-Facial Stereoselectivity in Thiophene 1-Oxide Cycloadditions.

Authors:  Brian J Levandowski; Dinushka Herath; Nathan M Gallup; K N Houk
Journal:  J Org Chem       Date:  2018-02-15       Impact factor: 4.354

2.  Prediction of 19F NMR Chemical Shifts for Fluorinated Aromatic Compounds.

Authors:  Carla Saunders; Mohammad B Khaled; Jimmie D Weaver; Dean J Tantillo
Journal:  J Org Chem       Date:  2018-02-26       Impact factor: 4.354

  2 in total

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