Literature DB >> 24313651

Phosphinecarboxamide: a phosphorus-containing analogue of urea and stable primary phosphine.

Andrew R Jupp1, Jose M Goicoechea.   

Abstract

Reactions of the 2-phosphaethynolate anion (PCO(-), 1) with ammonium salts quantitatively yielded phosphinecarboxamide (PH2C(O)NH2, 2). The molecular structure and chemical properties of 2 were studied by single-crystal X-ray diffraction and multielement NMR spectroscopy. This phosphorus-containing analogue of urea is a rare example of an air-stable primary phosphine.

Entities:  

Year:  2013        PMID： 24313651     DOI： 10.1021/ja4115693

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  12 in total

1.  Cyano(triphenylsilyl)phosphanide as a Building Block for P,C,N Conjugated Molecules.

Authors:  Grégoire Le Corre; Juan José Gamboa-Carballo; Zhongshu Li; Hansjörg Grützmacher
Journal:  Angew Chem Int Ed Engl       Date:  2021-10-20       Impact factor: 16.823

2.  A bis(silylene)-stabilized diphosphorus compound and its reactivity as a monophosphorus anion transfer reagent.

Authors:  Yuwen Wang; Tibor Szilvási; Shenglai Yao; Matthias Driess
Journal:  Nat Chem       Date:  2020-08-17       Impact factor: 24.427

3.  Exploiting the Brønsted acidity of phosphinecarboxamides for the synthesis of new phosphides and phosphines.

Authors:  Andrew R Jupp; Gemma Trott; Éléonore Payen de la Garanderie; James D G Holl; Duncan Carmichael; Jose M Goicoechea
Journal:  Chemistry       Date:  2015-04-17       Impact factor: 5.236

4.  Synthesis of anionic phosphorus-containing heterocycles by intramolecular cyclizations involving N-functionalized phosphinecarboxamides.

Authors:  Thomas P Robinson; Jose M Goicoechea
Journal:  Chemistry       Date:  2015-03-03       Impact factor: 5.236

5.  HPCO-A Phosphorus-Containing Analogue of Isocyanic Acid.

Authors:  Alexander Hinz; René Labbow; Chris Rennick; Axel Schulz; Jose M Goicoechea
Journal:  Angew Chem Int Ed Engl       Date:  2017-03-02       Impact factor: 15.336

6.  A Monoanionic Arsenide Source: Decarbonylation of the 2-Arsaethynolate Anion upon Reaction with Bulky Stannylenes.

Authors:  Alexander Hinz; Jose M Goicoechea
Journal:  Angew Chem Int Ed Engl       Date:  2016-11-15       Impact factor: 15.336

7.  Uranium and thorium complexes of the phosphaethynolate ion.

Authors:  Clément Camp; Nicholas Settineri; Julia Lefèvre; Andrew R Jupp; José M Goicoechea; Laurent Maron; John Arnold
Journal:  Chem Sci       Date:  2015-07-20       Impact factor: 9.825

8.  Ambient-Temperature Synthesis of 2-Phosphathioethynolate, PCS-, and the Ligand Properties of ECX- (E = N, P; X = O, S).

Authors:  Andrew R Jupp; Michael B Geeson; John E McGrady; Jose M Goicoechea
Journal:  Eur J Inorg Chem       Date:  2015-11-04       Impact factor: 2.524

9.  The 2-Arsaethynolate Anion: Synthesis and Reactivity Towards Heteroallenes.

Authors:  Alexander Hinz; Jose M Goicoechea
Journal:  Angew Chem Int Ed Engl       Date:  2016-04-20       Impact factor: 15.336

10.  Isolation of Au-, Co-η1PCO and Cu-η2PCO complexes, conversion of an Ir-η1PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion.

Authors:  Liu Liu; David A Ruiz; Fatme Dahcheh; Guy Bertrand; Riccardo Suter; Aaron M Tondreau; Hansjörg Grützmacher
Journal:  Chem Sci       Date:  2016-01-04       Impact factor: 9.825
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