| Literature DB >> 24310544 |
Gabriel E Schneider1, Henk J Bolink, Edwin C Constable, Cathrin D Ertl, Catherine E Housecroft, Antonio Pertegàs, Jennifer A Zampese, Andreas Kanitz, Florian Kessler, Sebastian B Meier.
Abstract
Small quantities of Cl(-) ions result in dramatic reductions in the performance of ionic transition metal complexes in light-emitting electrochemical cells. Strong ion-pairing between aromatic protons and chloride has been established in both the solid state and solution. X-ray structural determination of 2{[Ir(ppy)2(bpy)][Cl]}·2CH2Cl2·[H3O]·Cl reveals the unusual nature of an impurity encountered in the preparation of [Ir(ppy)2(bpy)][PF6].Entities:
Year: 2014 PMID： 24310544 DOI： 10.1039/c3dt53229a
Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390