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Literature DB >> 24307017

Hindered aryllithium reagents as partners in palladium-catalyzed cross-coupling: synthesis of tri- and tetra-ortho-substituted biaryls under ambient conditions.

Massimo Giannerini¹, Valentín Hornillos, Carlos Vila, Martín Fañanás-Mastral, Ben L Feringa.

Abstract

Entities: Chemical Species

Keywords: C-C coupling; biaryls; carbenes; organolithium compounds; palladium

Year: 2013 PMID： 24307017 DOI： 10.1002/anie.201306427

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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5 in total

1. Design, Synthesis, and Application of Polymer-Supported Silicon-Transfer Agents for Cross-Coupling Reactions with Organolithium Reagents.

Authors: Minh H Nguyen; Kevin T O'Brien; Amos B Smith
Journal: J Org Chem Date: 2017-10-02 Impact factor: 4.354

2. Computationally Assisted Mechanistic Investigation and Development of Pd-Catalyzed Asymmetric Suzuki-Miyaura and Negishi Cross-Coupling Reactions for Tetra-ortho-Substituted Biaryl Synthesis.

Authors: Nitinchandra Dahyabhai Patel; Joshua D Sieber; Sergei Tcyrulnikov; Bryan J Simmons; Daniel Rivalti; Krishnaja Duvvuri; Yongda Zhang; Donghong A Gao; Keith R Fandrick; Nizar Haddad; Kendricks So Lao; Hari Prasad Reddy Mangunuru; Soumik Biswas; Bo Qu; Nelu Grinberg; Scott Pennino; Heewon Lee; Jinhua J Song; B Frank Gupton; Neil K Garg; Marisa C Kozlowski; Chris H Senanayake
Journal: ACS Catal Date: 2018-09-20 Impact factor: 13.084

Hindered aryllithium reagents as partners in palladium-catalyzed cross-coupling: synthesis of tri- and tetra-ortho-substituted biaryls under ambient conditions.

1. Design, Synthesis, and Application of Polymer-Supported Silicon-Transfer Agents for Cross-Coupling Reactions with Organolithium Reagents.

2. Computationally Assisted Mechanistic Investigation and Development of Pd-Catalyzed Asymmetric Suzuki-Miyaura and Negishi Cross-Coupling Reactions for Tetra-ortho-Substituted Biaryl Synthesis.

3. Direct catalytic cross-coupling of alkenyllithium compounds.

4. Recyclable polystyrene-supported siloxane-transfer agent for palladium-catalyzed cross-coupling reactions.

5. Fast, greener and scalable direct coupling of organolithium compounds with no additional solvents.