Literature DB >> 24304362

Locked planarity: a strategy for tailoring ladder-type π-conjugated anilido-pyridine boron difluorides.

Qingshan Hao1, Shuai Yu, Shayu Li, Jinping Chen, Yi Zeng, Tianjun Yu, Guoqiang Yang, Yi Li.   

Abstract

A novel series of syn- and anti-ladder-type anilido-pyridine boron difluorides (APBDs) were synthesized by stepwise incorporation of boron into laddered ligands. The boron coordination-locked strategy endows the ladder-type APBDs with a stiff conformation, which results in a substantial bathochromic shift of their absorption spectra and a narrowed HOMO-LUMO energy gap, reinforcing the compounds for potential applications in organic electronics.

Entities:  

Year:  2013        PMID： 24304362     DOI： 10.1021/jo402583y

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  3 in total

1.  Enhancing electron affinity and tuning band gap in donor-acceptor organic semiconductors by benzothiadiazole directed C-H borylation.

Authors:  D L Crossley; I A Cade; E R Clark; A Escande; M J Humphries; S M King; I Vitorica-Yrezabal; M J Ingleson; M L Turner
Journal:  Chem Sci       Date:  2015-06-12       Impact factor: 9.825

Review 2.  BN Embedded Polycyclic π-Conjugated Systems: Synthesis, Optoelectronic Properties, and Photovoltaic Applications.

Authors:  Jianhua Huang; Yuqing Li
Journal:  Front Chem       Date:  2018-08-07       Impact factor: 5.221

3.  Highly Emissive Far Red/Near-IR Fluorophores Based on Borylated Fluorene-Benzothiadiazole Donor-Acceptor Materials.

Authors:  Daniel L Crossley; Inigo Vitorica-Yrezabal; Martin J Humphries; Michael L Turner; Michael J Ingleson
Journal:  Chemistry       Date:  2016-07-27       Impact factor: 5.236
  3 in total

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