Literature DB >> 24296648

Unprecedented organocatalytic reduction of lignin model compounds to phenols and primary alcohols using hydrosilanes.

Elias Feghali1, Thibault Cantat.   

Abstract

The first metal-free reduction of lignin model compounds is described. Using inexpensive Et3SiH, PMHS and TMDS hydrosilanes as reductants, α-O-4 and β-O-4 linkages are reduced to primary alcohols and phenols under mild conditions using B(C6F5)3 as an efficient catalyst.

Entities:  

Year:  2014        PMID： 24296648     DOI： 10.1039/c3cc47655c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

Review 1.  Activation of Si-H and B-H bonds by Lewis acidic transition metals and p-block elements: same, but different.

Authors:  Pablo Ríos; Amor Rodríguez; Salvador Conejero
Journal:  Chem Sci       Date:  2022-06-06       Impact factor: 9.969

Review 2.  Paving the Way for Lignin Valorisation: Recent Advances in Bioengineering, Biorefining and Catalysis.

Authors:  Roberto Rinaldi; Robin Jastrzebski; Matthew T Clough; John Ralph; Marco Kennema; Pieter C A Bruijnincx; Bert M Weckhuysen
Journal:  Angew Chem Int Ed Engl       Date:  2016-06-17       Impact factor: 15.336

3.  Heteroatom-assisted olefin polymerization by rare-earth metal catalysts.

Authors:  Chunxiang Wang; Gen Luo; Masayoshi Nishiura; Guoyong Song; Atsushi Yamamoto; Yi Luo; Zhaomin Hou
Journal:  Sci Adv       Date:  2017-07-21       Impact factor: 14.136

Review 4.  Defunctionalisation catalysed by boron Lewis acids.

Authors:  Huaquan Fang; Martin Oestreich
Journal:  Chem Sci       Date:  2020-07-28       Impact factor: 9.825

Review 5.  An Introduction to Model Compounds of Lignin Linking Motifs; Synthesis and Selection Considerations for Reactivity Studies.

Authors:  Ciaran W Lahive; Paul C J Kamer; Christopher S Lancefield; Peter J Deuss
Journal:  ChemSusChem       Date:  2020-07-09       Impact factor: 8.928
  5 in total

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