Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Silicon-oxygen double bonds: a stable silanone with a trigonal-planar coordinated silicon center.

Literature DB >> 24288183

Silicon-oxygen double bonds: a stable silanone with a trigonal-planar coordinated silicon center.

Alexander C Filippou¹, Bernhard Baars, Oleg Chernov, Yury N Lebedev, Gregor Schnakenburg.

Abstract

SiO in a complex: The first silanone that is stable at room temperature (3) is reported. The two-step synthesis involves carbonylation of the silylidyne complex 1 to give the chromiosilylene 2, followed by oxidation of 2 with N2 O. Silanone 3 features a polar, short SiO bond (1.526(3) Å) to a trigonal-planar-coordinated silicon center and reacts with water to give the dihydroxysilyl complex.

Entities: Chemical

Keywords: chromium; silanones; silicon; silylenes; silylidynes

Year: 2013 PMID： 24288183 DOI： 10.1002/anie.201308433

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

Keyword Cloud
Cited

15 in total

1. Main group chemistry: Small silicon oxides isolated.

Authors: Yitzhak Apeloig
Journal: Nat Chem Date: 2015-06 Impact factor: 24.427

2. Stabilization of elusive silicon oxides.

Authors: Yuzhong Wang; Mingwei Chen; Yaoming Xie; Pingrong Wei; Henry F Schaefer; Paul von R Schleyer; Gregory H Robinson
Journal: Nat Chem Date: 2015-04-20 Impact factor: 24.427

3. Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(N₃)]^.

Authors: Anindya K Swarnakar; Christian Hering-Junghans; Michael J Ferguson; Robert McDonald; Eric Rivard
Journal: Chem Sci Date: 2016-12-19 Impact factor: 9.825

4. Facile Access to Dative, Single, and Double Silicon-Metal Bonds Through M-Cl Insertion Reactions of Base-Stabilized Si^II Cations.

Authors: Philipp Frisch; Tibor Szilvási; Shigeyoshi Inoue
Journal: Chemistry Date: 2020-04-28 Impact factor: 5.236

5. Treatment of Silylene-Phosphinidene with Chalcogens Resulted Exclusively in the Formation of Silicon-Bonded Chalcogens.

Authors: Soumen Sinhababu; Mujahuddin M Siddiqui; Samir Kumar Sarkar; Annika Münch; Regine Herbst-Irmer; Anjana George; Pattiyil Parameswaran; Dietmar Stalke; Herbert W Roesky
Journal: Chemistry Date: 2019-08-13 Impact factor: 5.236

Silicon-oxygen double bonds: a stable silanone with a trigonal-planar coordinated silicon center.

1. Main group chemistry: Small silicon oxides isolated.

2. Stabilization of elusive silicon oxides.

3. Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(N₃)]^.

4. Facile Access to Dative, Single, and Double Silicon-Metal Bonds Through M-Cl Insertion Reactions of Base-Stabilized Si^II Cations.

5. Treatment of Silylene-Phosphinidene with Chalcogens Resulted Exclusively in the Formation of Silicon-Bonded Chalcogens.

6. An Isolable Bis(Silanone-Borane) Adduct.

7. Synthesis and Hydrogenation of Heavy Homologues of Rhodium Carbynes: [(Me₃ P)₂ (Ph₃ P)Rh≡E-Ar*] (E=Sn, Pb).

Review 8. Acid-Base Free Main Group Carbonyl Analogues.

9. Distannabarrelenes with Three Coordinated Sn^II Atoms.

10. Interconversion and reactivity of manganese silyl, silylene, and silene complexes.