Literature DB >> 24288039

Base-free hydrogen generation from methanol using a bi-catalytic system.

Angèle Monney1, Enrico Barsch, Peter Sponholz, Henrik Junge, Ralf Ludwig, Matthias Beller.   

Abstract

A bi-catalytic system, in which Ru-MACHO-BH and Ru(H)2(dppe)2 interact in a synergistic manner, was developed for the base-free dehydrogenation of methanol. A total TON > 4200 was obtained with only trace amounts of CO contamination (<8 ppm) in the produced gas.

Entities:  

Year:  2013        PMID： 24288039     DOI： 10.1039/c3cc47306f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  8 in total

Review 1.  Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics.

Authors:  Amit Kumar; Prosenjit Daw; David Milstein
Journal:  Chem Rev       Date:  2021-11-02       Impact factor: 60.622

2.  Reactivity of a Ruthenium-Carbonyl Complex in the Methanol Dehydrogenation Reaction.

Authors:  Fenna F van de Watering; Martin Lutz; Wojciech I Dzik; Bas de Bruin; Joost N H Reek
Journal:  ChemCatChem       Date:  2016-08-18       Impact factor: 5.686

3.  Homogeneously catalysed conversion of aqueous formaldehyde to H2 and carbonate.

Authors:  M Trincado; Vivek Sinha; Rafael E Rodriguez-Lugo; Bruno Pribanic; Bas de Bruin; Hansjörg Grützmacher
Journal:  Nat Commun       Date:  2017-04-28       Impact factor: 14.919

4.  Hydrogen generation from methanol at near-room temperature.

Authors:  Yangbin Shen; Yulu Zhan; Shuping Li; Fandi Ning; Ying Du; Yunjie Huang; Ting He; Xiaochun Zhou
Journal:  Chem Sci       Date:  2017-09-20       Impact factor: 9.825

5.  Cyclometalated Ruthenium Pincer Complexes as Catalysts for the α-Alkylation of Ketones with Alcohols.

Authors:  Patrick Piehl; Roberta Amuso; Elisabetta Alberico; Henrik Junge; Bartolo Gabriele; Helfried Neumann; Matthias Beller
Journal:  Chemistry       Date:  2020-03-09       Impact factor: 5.236

6.  DFT Provides Insight into the Additive-Free Conversion of Aqueous Methanol to Dihydrogen Catalyzed by [Ru(trop2dad)]: Importance of the (Electronic) Flexibility of the Diazadiene Moiety.

Authors:  Vivek Sinha; Monica Trincado; Hansjörg Grützmacher; Bas de Bruin
Journal:  J Am Chem Soc       Date:  2018-10-01       Impact factor: 15.419

Review 7.  Sustainable catalysis with fluxional acridine-based PNP pincer complexes.

Authors:  Sayan Kar; David Milstein
Journal:  Chem Commun (Camb)       Date:  2022-03-18       Impact factor: 6.222

8.  Sustainable production of hydrogen with high purity from methanol and water at low temperatures.

Authors:  Sai Zhang; Yuxuan Liu; Mingkai Zhang; Yuanyuan Ma; Jun Hu; Yongquan Qu
Journal:  Nat Commun       Date:  2022-09-21       Impact factor: 17.694
  8 in total

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