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Literature DB >> 24282827

A cubic dipole lattice of water molecules trapped inside carbon cages.

Shinobu Aoyagi¹, Norihisa Hoshino, Tomoyuki Akutagawa, Yuki Sado, Ryo Kitaura, Hisanori Shinohara, Kunihisa Sugimoto, Rui Zhang, Yasujiro Murata.

Abstract

We report the crystal structure and dielectric properties of a pure H2O@C60 crystal at low temperature. The caged water molecules free from the hydrogen bonds rotate even at 8 K. The antifreeze rotating water molecules respond to an external electric field due to their permanent dipole moment.

Entities: Chemical

Year: 2013 PMID： 24282827 DOI： 10.1039/c3cc46683c

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

5 in total

1. The dipolar endofullerene HF@C60.

Authors: Andrea Krachmalnicoff; Richard Bounds; Salvatore Mamone; Shamim Alom; Maria Concistrè; Benno Meier; Karel Kouřil; Mark E Light; Mark R Johnson; Stéphane Rols; Anthony J Horsewill; Anna Shugai; Urmas Nagel; Toomas Rõõm; Marina Carravetta; Malcolm H Levitt; Richard J Whitby
Journal: Nat Chem Date: 2016-07-11 Impact factor: 24.427

A cubic dipole lattice of water molecules trapped inside carbon cages.

1. The dipolar endofullerene HF@C60.

2. Probing the interaction between the encapsulated water molecule and the fullerene cages in H₂O@C₆₀^- and H₂O@C₅₉N^.

3. Unraveling the Origin of Symmetry Breaking in H₂ O@C₆₀ Endofullerene Through Quantum Computations.

4. Electrical detection of ortho-para conversion in fullerene-encapsulated water.

5. Structure of [60]fullerene with a mobile lithium cation inside.

A cubic dipole lattice of water molecules trapped inside carbon cages.

1. The dipolar endofullerene HF@C60.

2. Probing the interaction between the encapsulated water molecule and the fullerene cages in H2O@C60- and H2O@C59N.

3. Unraveling the Origin of Symmetry Breaking in H2 O@C60 Endofullerene Through Quantum Computations.

4. Electrical detection of ortho-para conversion in fullerene-encapsulated water.

5. Structure of [60]fullerene with a mobile lithium cation inside.

2. Probing the interaction between the encapsulated water molecule and the fullerene cages in H₂O@C₆₀^- and H₂O@C₅₉N^.

3. Unraveling the Origin of Symmetry Breaking in H₂ O@C₆₀ Endofullerene Through Quantum Computations.