Literature DB >> 24281888

A cerium(IV)-carbon multiple bond.

Matthew Gregson1, Erli Lu, Jonathan McMaster, William Lewis, Alexander J Blake, Stephen T Liddle.   

Abstract

Straightforward access to a cerium(IV)-carbene complex was provided by one-electron oxidation of an anionic "ate" cerium(III)-carbene precursor, thereby avoiding decomposition reactions that plague oxidations of neutral cerium(III) compounds. The cerium(IV)-carbene complex is the first lanthanide(IV)-element multiple bond and involves a twofold bonding interaction of two electron pairs between cerium and carbon.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  carbenes; cerium; density functional theory; lanthanides; multiple bonding

Year:  2013        PMID： 24281888     DOI： 10.1002/anie.201306984

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  8 in total

1.  The ketimide ligand is not just an inert spectator: heteroallene insertion reactivity of an actinide-ketimide linkage in a thorium carbene amide ketimide complex.

Authors:  Erli Lu; William Lewis; Alexander J Blake; Stephen T Liddle
Journal:  Angew Chem Int Ed Engl       Date:  2014-07-07       Impact factor: 15.336

2.  Synthesis of a terminal Ce(iv) oxo complex by photolysis of a Ce(iii) nitrate complex.

Authors:  Mikiyas K Assefa; Guang Wu; Trevor W Hayton
Journal:  Chem Sci       Date:  2017-09-27       Impact factor: 9.825

3.  The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes.

Authors:  Matthew Gregson; Erli Lu; David P Mills; Floriana Tuna; Eric J L McInnes; Christoph Hennig; Andreas C Scheinost; Jonathan McMaster; William Lewis; Alexander J Blake; Andrew Kerridge; Stephen T Liddle
Journal:  Nat Commun       Date:  2017-02-03       Impact factor: 14.919

4.  Rare-Earth- and Uranium-Mesoionic Carbenes: A New Class of f-Block Carbene Complex Derived from an N-Heterocyclic Olefin.

Authors:  John A Seed; Matthew Gregson; Floriana Tuna; Nicholas F Chilton; Ashley J Wooles; Eric J L McInnes; Stephen T Liddle
Journal:  Angew Chem Int Ed Engl       Date:  2017-08-09       Impact factor: 15.336

5.  Emergence of the structure-directing role of f-orbital overlap-driven covalency.

Authors:  Erli Lu; Saira Sajjad; Victoria E J Berryman; Ashley J Wooles; Nikolas Kaltsoyannis; Stephen T Liddle
Journal:  Nat Commun       Date:  2019-02-07       Impact factor: 14.919

6.  Isolation and characterization of a covalent CeIV-Aryl complex with an anomalous 13C chemical shift.

Authors:  Grace B Panetti; Dumitru-Claudiu Sergentu; Michael R Gau; Patrick J Carroll; Jochen Autschbach; Patrick J Walsh; Eric J Schelter
Journal:  Nat Commun       Date:  2021-03-17       Impact factor: 14.919

7.  Carbene Complexes of Neptunium.

Authors:  Conrad A P Goodwin; Ashley J Wooles; Jesse Murillo; Erli Lu; Josef T Boronski; Brian L Scott; Andrew J Gaunt; Stephen T Liddle
Journal:  J Am Chem Soc       Date:  2022-05-24       Impact factor: 16.383

8.  Reappraising Schmidpeter's bis(iminophosphoranyl)phosphides: coordination to transition metals and bonding analysis.

Authors:  Adrien T Normand; E Daiann Sosa Carrizo; Corentin Magnoux; Esteban Lobato; Hélène Cattey; Philippe Richard; Stéphane Brandès; Charles H Devillers; Anthony Romieu; Pierre Le Gendre; Paul Fleurat-Lessard
Journal:  Chem Sci       Date:  2020-10-26       Impact factor: 9.825
  8 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.