| Literature DB >> 24281880 |
Tomohiro Seki1, Kenta Sakurada, Hajime Ito.
Abstract
Green and blue polymorphs: A single-crystal-to-single-crystal (SCSC) phase transition of phenyl(3,5-dimethylphenyl isocyanide)gold(I) was triggered by mechanical picking or solid seeding and propagated spontaneously with a domino-like mechanism. As a result, one phase with intense green emission was transformed to another phase with weaker blue emission.Entities:
Keywords: aurophilic interactions; emission; luminescence; phase transitions; polymorphism; single crystals
Year: 2013 PMID: 24281880 DOI: 10.1002/anie.201307672
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336