Literature DB >> 24280865

Tandem synthesis of 3-allyl-chromones from alkynones and allylic alcohols under metal-free conditions.

Xuesong Wang1, Guolin Cheng, Xiuling Cui.   

Abstract

A novel and efficient approach to 3-allyl-chromones from alkynones and allylic alcohols via a tandem Michael addition-Claisen rearrangement-O-arylation reaction has been developed. Diversely structural 3-allyl-chromones were afforded in up to 93% yield for 24 examples. This synthetic strategy is regiospecific, highly efficient, environment friendly and metal-free.

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Year:  2013        PMID: 24280865     DOI: 10.1039/c3cc48259f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Transition-metal-free synthesis of 3-sulfenylated chromones via KIO3-catalyzed radical C(sp2)-H sulfenylation.

Authors:  Yanhui Guo; Shanshan Zhong; Li Wei; Jie-Ping Wan
Journal:  Beilstein J Org Chem       Date:  2017-09-27       Impact factor: 2.883

  1 in total

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