Literature DB >> 24263253

Recent trends in Pd-catalyzed remote functionalization of carbonyl compounds.

Ivan Franzoni1, Clément Mazet.   

Abstract

Recent advances in the palladium-catalyzed remote functionalization of carbonyl derivatives are highlighted in this review. The structure of the article is based on the three strategies that have emerged in recent years as the most viable tactics to construct C(sp(3))-C, C(sp(3))-N or C(sp(3))-O bonds at a distance of at least three carbon atoms from the carbonyl functionality. The specific aspects of each of these approaches are discussed in detail (reaction conditions, substrate scope and limitations). As the reading progresses, their complementarity should also appear clearly.

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Year:  2014        PMID: 24263253     DOI: 10.1039/c3ob42050g

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN: 1477-0520            Impact factor:   3.876


  11 in total

1.  Palladium-Catalyzed Chemoselective Activation of sp3 vs sp2 C-H Bonds: Oxidative Coupling To Form Quaternary Centers.

Authors:  Gang Hong; Pradip D Nahide; Uday Kumar Neelam; Peter Amadeo; Arjun Vijeta; John M Curto; Charles E Hendrick; Kelsey F VanGelder; Marisa C Kozlowski
Journal:  ACS Catal       Date:  2019-03-08       Impact factor: 13.084

2.  Olefination via Cu-Mediated Dehydroacylation of Unstrained Ketones.

Authors:  Xukai Zhou; Yan Xu; Guangbin Dong
Journal:  J Am Chem Soc       Date:  2021-11-22       Impact factor: 16.383

3.  Catalytic enantioselective arylative cyclizations of alkynyl 1,3-diketones by 1,4-rhodium(i) migration.

Authors:  Alistair Groves; Jinwei Sun; Hal R I Parke; Michael Callingham; Stephen P Argent; Laurence J Taylor; Hon Wai Lam
Journal:  Chem Sci       Date:  2020-02-06       Impact factor: 9.825

4.  A unique Pd-catalysed Heck arylation as a remote trigger for cyclopropane selective ring-opening.

Authors:  Sukhdev Singh; Jeffrey Bruffaerts; Alexandre Vasseur; Ilan Marek
Journal:  Nat Commun       Date:  2017-02-07       Impact factor: 14.919

5.  Exploring the mechanism of the Pd-catalyzed spirocyclization reaction: a combined DFT and experimental study.

Authors:  Ivan Franzoni; Hyung Yoon; José-Antonio García-López; Amalia Isabel Poblador-Bahamonde; Mark Lautens
Journal:  Chem Sci       Date:  2017-12-08       Impact factor: 9.825

6.  Remote functionalization of hydrocarbons with reversibility enhanced stereocontrol.

Authors:  Alexandre Vasseur; Lionel Perrin; Odile Eisenstein; Ilan Marek
Journal:  Chem Sci       Date:  2015-03-03       Impact factor: 9.825

7.  Ni-catalyzed migratory fluoro-alkenylation of unactivated alkyl bromides with gem-difluoroalkenes.

Authors:  Lu Zhou; Chuan Zhu; Peijia Bi; Chao Feng
Journal:  Chem Sci       Date:  2018-11-09       Impact factor: 9.825

8.  Ru-catalyzed isomerization of ω-alkenylboronates towards stereoselective synthesis of vinylboronates with subsequent in situ functionalization.

Authors:  Guo-Ming Ho; Lucas Segura; Ilan Marek
Journal:  Chem Sci       Date:  2020-05-26       Impact factor: 9.825

9.  Coordinating activation strategy for C(sp(3))-H/C(sp(3))-H cross-coupling to access β-aromatic α-amino acids.

Authors:  Kaizhi Li; Qian Wu; Jingbo Lan; Jingsong You
Journal:  Nat Commun       Date:  2015-09-29       Impact factor: 14.919

10.  Chemo- and regioselective oxygenation of C(sp3)-H bonds in aliphatic alcohols using a covalently bound directing activator and atmospheric oxygen.

Authors:  Jun Ozawa; Masayuki Tashiro; Jizhi Ni; Kounosuke Oisaki; Motomu Kanai
Journal:  Chem Sci       Date:  2015-11-27       Impact factor: 9.825

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