Literature DB >> 24252869

Photoreactivity of polymorphs of a ladder polymer with criss-cross and parallel orientations of C=C bonds.

Anjana Chanthapally1, Wei Ting Oh, Jagadese J Vittal.   

Abstract

Two polymorphic forms of a ladder coordination polymer [Zn2(μ-O2C-p-Tol)2(O2C-p-Tol)2(bpe)2] have parallel and criss-cross alignments of the C=C bond pairs. Both polymorphs undergo 100% [2+2] cycloaddition reaction but the one with a parallel orientation of C=C bonds (thermodynamic product) retains its single crystallinity after the reaction.

Entities:  

Year:  2014        PMID： 24252869     DOI： 10.1039/c3cc47816e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Light-triggered Supramolecular Isomerism in a Self-catenated Zn(II)-organic Framework: Dynamic Photo-switching CO2 Uptake and Detection of Nitroaromatics.

Authors:  Wei-Chao Song; Xun-Zhe Cui; Zhong-Yi Liu; En-Cui Yang; Xiao-Jun Zhao
Journal:  Sci Rep       Date:  2016-10-11       Impact factor: 4.379

2.  Exploitation of knowledge databases in the synthesis of zinc(II) malonates with photo-sensitive and photo-insensitive N,N'-containing linkers.

Authors:  Ekaterina N Zorina-Tikhonova; Aleksandr S Chistyakov; Mikhail A Kiskin; Aleksei A Sidorov; Pavel V Dorovatovskii; Yan V Zubavichus; Eugenia D Voronova; Ivan A Godovikov; Alexander A Korlyukov; Igor L Eremenko; Anna V Vologzhanina
Journal:  IUCrJ       Date:  2018-03-27       Impact factor: 4.769
  2 in total

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