| Literature DB >> 24249769 |
Stefan Adams1, Nicolas Dirr, Mark Peletier, Johannes Zimmer.
Abstract
In recent work we uncovered intriguing connections between Otto's characterization of diffusion as an entropic gradient flow on the one hand and large-deviation principles describing the microscopic picture (Brownian motion) on the other. In this paper, we sketch this connection, show how it generalizes to a wider class of systems and comment on consequences and implications. Specifically, we connect macroscopic gradient flows with large-deviation principles, and point out the potential of a bigger picture emerging: we indicate that, in some non-equilibrium situations, entropies and thermodynamic free energies can be derived via large-deviation principles. The approach advocated here is different from the established hydrodynamic limit passage but extends a link that is well known in the equilibrium situation.Keywords: Wasserstein gradient flow; large-deviation theory; non-equilibrium system
Year: 2013 PMID: 24249769 DOI: 10.1098/rsta.2012.0341
Source DB: PubMed Journal: Philos Trans A Math Phys Eng Sci ISSN: 1364-503X Impact factor: 4.226