Literature DB >> 24248822

The structures of the [M-H] anions of the CH3NO 2 isomers nitromethane and methyl nitrite.

D A Thomas1, J E Bloor, J E Bartmess.   

Abstract

The 60-u anion observed in the ion/molecule chemistry of methyl nitrite is shown to have the structure O=NCH2O(-), and not that of the expected deprotonation product (-)CH2ONO, by the use of mass-analyzed ion kinetic energy spectrometry, ion/molecule reactivity, and ab initio calculations.

Entities:  

Year:  1990        PMID: 24248822     DOI: 10.1016/1044-0305(90)85004-6

Source DB:  PubMed          Journal:  J Am Soc Mass Spectrom        ISSN: 1044-0305            Impact factor:   3.109


  1 in total

1.  Preparation and some properties of stable and carbon-14 and tritium-labeled short-chain aliphatic hydroxamic acids.

Authors:  W N Fishbein; J Daly; C L Streeter
Journal:  Anal Biochem       Date:  1969-04-04       Impact factor: 3.365

  1 in total

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