| Literature DB >> 24243663 |
Yoichi M A Yamada1, Yoshinari Yuyama, Takuma Sato, Shigenori Fujikawa, Yasuhiro Uozumi.
Abstract
We report the development of a silicon nanowire array-stabilized palladium nanoparticle catalyst, SiNA-Pd. Its use in the palladium-catalyzed Mizoroki-Heck reaction, the hydrogenation of an alkene, the hydrogenolysis of nitrobenzene, the hydrosilylation of an α,β-unsaturated ketone, and the C-H bond functionalization reactions of thiophenes and indoles achieved a quantitative production with high reusability. The catalytic activity reached several hundred-mol ppb of palladium, reaching a TON of 2 000 000.Entities:
Keywords: CH bond functionalization; Mizoroki-Heck reaction; ozagrel; palladium nanoparticle; silicon-nanowire array
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Year: 2013 PMID: 24243663 DOI: 10.1002/anie.201308541
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336