| Literature DB >> 24228898 |
Xiaoqian Sun1, Youran Lyu, Daisy Zhang-Negrerie, Yunfei Du, Kang Zhao.
Abstract
A variety of enaminones and enamine carboxylic esters were converted to trifluoroethoxylated 2H-azirines through reactions with PhIO in trifluoroethanol (TFE). The cascade reaction is postulated to proceed via a PhIO-mediated oxidative trifluoroethoxylation and a subsequent azirination of the α-trifluoroethoxylated enamine intermediates.Entities:
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Year: 2013 PMID： 24228898 DOI： 10.1021/ol4030716
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005