Literature DB >> 24225771

Palladium-catalyzed stereospecific cross-coupling of enantioenriched allylic alcohols with boronic acids.

Hai-Bian Wu1, Xian-Tao Ma, Shi-Kai Tian.   

Abstract

In the presence of 2.5 mol% Pd2(dba)3-TMEDA (1 : 4), a range of enantioenriched allylic alcohols smoothly coupled with boronic acids in a highly regioselective fashion with inversion of configuration to afford structurally diverse alkenes in good yields with perfect retention of ee.

Entities:  

Year:  2014        PMID： 24225771     DOI： 10.1039/c3cc45772a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

Review 1.  Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C Bonds.

Authors:  Alan H Cherney; Nathaniel T Kadunce; Sarah E Reisman
Journal:  Chem Rev       Date:  2015-08-13       Impact factor: 60.622

2.  Nickel-Catalyzed, Stereospecific C-C and C-B Cross-Couplings via C-N and C-O Bond Activation.

Authors:  Jianyu Xu; Olivia P Bercher; Michael R Talley; Mary P Watson
Journal:  ACS Catal       Date:  2021-01-19       Impact factor: 13.084

3.  Interrupting the Barton-McCombie Reaction: Aqueous Deoxygenative Trifluoromethylation of O-Alkyl Thiocarbonates.

Authors:  Zhi-Yun Liu; Silas P Cook
Journal:  Org Lett       Date:  2021-01-14       Impact factor: 6.072

4.  Enantiospecific, nickel-catalyzed cross-couplings of allylic pivalates and arylboroxines.

Authors:  Harathi D Srinivas; Qi Zhou; Mary P Watson
Journal:  Org Lett       Date:  2014-06-13       Impact factor: 6.005

5.  Mechanistic Study on Allylic Arylation in Water with Linear Polystyrene-Stabilized Pd and PdO Nanoparticles.

Authors:  Atsushi Ohtaka; Misa Kawase; Akira Usami; Shiho Fukui; Mana Yamashita; Kazuki Yamaguchi; Akira Sakon; Tomoya Shiraki; Taiki Ishida; Soma Nagata; Yuji Kimura; Go Hamasaka; Yasuhiro Uozumi; Tsutomu Shinagawa; Osamu Shimomura; Ryôki Nomura
Journal:  ACS Omega       Date:  2019-09-13
  5 in total

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