| Literature DB >> 24202546 |
Matthias Müller1, Cäcilia Maichle-Mössmer, Holger F Bettinger.
Abstract
The irradiation of 2-azido-4,4,5,5-tetramethyl-1,3,2-dioxaborol (pinBN3, pin = pinacolato) generates the corresponding borylnitrene that easily inserts into the CH bond of tetramethylsilane. This primary photoproduct, a monoborylated aminoborane, undergoes a subsequent reaction with pinBN3 forming a bisborylated aminoborane.Entities:
Year: 2013 PMID： 24202546 DOI： 10.1039/c3cc47753c
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222