| Literature DB >> 24180555 |
Nolan M Betterley1, Panida Surawatanawong, Samran Prabpai, Palangpon Kongsaeree, Chutima Kuhakarn, Manat Pohmakotr, Vichai Reutrakul.
Abstract
Electrophilic difluoro(phenylthio)methylation of allylsilanes has been achieved using bromodifluoro(phenylthio)methane (PhSCF2Br) and silver hexafluoroantimonate (AgSbF6). The structural assignment and observation of α-fluorocarbocation were substantiated by NMR and theoretical calculations. Detailed mechanistic and electronic studies have provided a fundamental understanding of the reactivity and stability of the difluoro(phenylthio)methylium cation (PhSCF2(+)).Entities:
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Year: 2013 PMID： 24180555 DOI： 10.1021/ol402631t
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005