Literature DB >> 24175316

A mechanistic investigation of hydrodehalogenation using ESI-MS.

Zohrab Ahmadi1, J Scott McIndoe.   

Abstract

The rate of hydrodehalogenation of aryl iodides with a palladium catalyst in methanol exhibits a strong primary kinetic isotope effect from both CD3OD and CH3OD, suggesting that deprotonation plays a major role in the mechanism.

Entities:  

Year:  2013        PMID： 24175316     DOI： 10.1039/c3cc46271d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Microflowers formed by complexation-driven self-assembly between palladium(ii) and bis-theophyllines: immortal catalyst for C-C cross-coupling reactions.

Authors:  Katsuya Kaikake; Naoki Jou; Go Shitara; Ren-Hua Jin
Journal:  RSC Adv       Date:  2021-11-02       Impact factor: 4.036

2.  Mixed-halide triphenyl methyl radicals for site-selective functionalization and polymerization.

Authors:  Lisa Chen; Mona Arnold; Rémi Blinder; Fedor Jelezko; Alexander J C Kuehne
Journal:  RSC Adv       Date:  2021-08-13       Impact factor: 3.361

3.  Rapid Access to Azabicyclo[3.3.1]nonanes by a Tandem Diverted Tsuji-Trost Process.

Authors:  Hannah G Steeds; Jonathan P Knowles; Wai L Yu; Jeffery Richardson; Katie G Cooper; Kevin I Booker-Milburn
Journal:  Chemistry       Date:  2020-10-06       Impact factor: 5.236
  3 in total

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