| Literature DB >> 24170291 |
Tatsuo Ishiyama1, Takeaki Saiki, Emi Kishida, Ikuo Sasaki, Hajime Ito, Norio Miyaura.
Abstract
Aromatic C-H silylation of neat arenes with 1-hydrosilatrane was found to be efficiently catalyzed by iridium catalysts composed of 1/2[Ir(OMe)(cod)]2 and 2,9-dimethyl-1,10-phenanthroline at 120 °C to afford the corresponding silylated products in high yields. The silylated products can be used for the Hiyama cross-coupling reaction.Entities:
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Year: 2013 PMID： 24170291 DOI： 10.1039/c3ob41623b
Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.876