Literature DB >> 24162511

Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene complex.

Polly L Arnold1, Isobel A Marr, Sergey Zlatogorsky, Ronan Bellabarba, Robert P Tooze.   

Abstract

A Sc NHC complex readily activates three equivalents of CO2 showing 'Frustrated Lewis Pair' type reactivity with each metal-carbene bond, but whilst CS2 is also activated by the labile carbenes, no metal involvement is observed.

Entities:  

Year:  2014        PMID： 24162511     DOI： 10.1039/c3dt52762j

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  2 in total

1.  Unraveling differences in aluminyl and carbene coordination chemistry: bonding in gold complexes and reactivity with carbon dioxide.

Authors:  Diego Sorbelli; Leonardo Belpassi; Paola Belanzoni
Journal:  Chem Sci       Date:  2022-03-31       Impact factor: 9.969

Review 2.  Recent Advances in Catalysis Involving Bidentate N-Heterocyclic Carbene Ligands.

Authors:  Abdollah Neshat; Piero Mastrorilli; Ali Mousavizadeh Mobarakeh
Journal:  Molecules       Date:  2021-12-24       Impact factor: 4.411
  2 in total

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