Literature DB >> 24158694

Synthesis of rac-Lindenene via a thermally induced cyclopropanation reaction.

Thomas W Fenlon1, Michael W Jones, Robert M Adlington, Victor Lee.   

Abstract

The first synthesis of the sesquiterpene Lindenene is described. A novel non-catalysed intramolecular cyclopropanation reaction between a diazoketone and an unactivated alkene was utilised to construct the relatively labile ketone precursor with complete stereocontrol. This ketone was transformed in three steps into Lindenene.

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Year:  2013        PMID： 24158694     DOI： 10.1039/c3ob41716f

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN： 1477-0520            Impact factor:   3.876


  4 in total

1.  Reanalysis of Lindenatriene, a Building Block for the Synthesis of Lindenane Oligomers.

Authors:  Ruben M Martinez; Hannah E Burdge; Ryan A Shenvi
Journal:  Tetrahedron       Date:  2019-03-14       Impact factor: 2.457

2.  Atypical Lindenane-Type Sesquiterpenes from Lindera myrrha.

Authors:  Thuc-Huy Duong; Mehdi A Beniddir; Nguyen T Trung; Cam-Tu D Phan; Van Giau Vo; Van-Kieu Nguyen; Quynh-Loan Le; Hoang-Dung Nguyen; Pierre Le Pogam
Journal:  Molecules       Date:  2020-04-16       Impact factor: 4.411

3.  A unified strategy toward total syntheses of lindenane sesquiterpenoid [4 + 2] dimers.

Authors:  Biao Du; Zhengsong Huang; Xiao Wang; Ting Chen; Guo Shen; Shaomin Fu; Bo Liu
Journal:  Nat Commun       Date:  2019-04-23       Impact factor: 14.919

4.  Total syntheses of shizukaols A and E.

Authors:  Jian-Li Wu; Yin-Suo Lu; Bencan Tang; Xiao-Shui Peng
Journal:  Nat Commun       Date:  2018-10-02       Impact factor: 14.919
  4 in total

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