Literature DB >> 24158159

A stable 16-electron iridium(III) hydride complex grafted on SBA-15: a single-site catalyst for alkene hydrogenation.

Martino Rimoldi1, Daniel Fodor, Jeroen A van Bokhoven, Antonio Mezzetti.   

Abstract

The dihydride pincer complex [IrH2(POCOP)] reacts with surface silanols of mesoporous silica (SBA-15) to give the coordinatively unsaturated, yet stable hydridesiloxo Ir(III) species [IrH(O-SBA-15)(POCOP)]. The silica-grafted complex catalyses the hydrogenation of ethene and propene at low temperature and pressure without prior activation.

Entities:  

Year:  2013        PMID： 24158159     DOI： 10.1039/c3cc47296e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  A metal-organic framework immobilised iridium pincer complex.

Authors:  Martino Rimoldi; Akitake Nakamura; Nicolaas A Vermeulen; James J Henkelis; Anthea K Blackburn; Joseph T Hupp; J Fraser Stoddart; Omar K Farha
Journal:  Chem Sci       Date:  2016-05-10       Impact factor: 9.825

2.  Immobilization of an Iridium Pincer Complex in a Microporous Polymer for Application in Room-Temperature Gas Phase Catalysis.

Authors:  Michaela König; Massimo Rigo; Nicolas Chaoui; Trung Tran Ngoc; Jan Dirk Epping; Johannes Schmidt; Pradip Pachfule; Meng-Yang Ye; Matthias Trunk; Johannes F Teichert; Matthias Drieß; Arne Thomas
Journal:  Angew Chem Int Ed Engl       Date:  2020-08-31       Impact factor: 15.336
  2 in total

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