| Literature DB >> 24156658 |
Tatsuki Morimoto1, Takuya Nakajima, Shuhei Sawa, Ryoichi Nakanishi, Daisuke Imori, Osamu Ishitani.
Abstract
A rhenium(I) tricarbonyl diimine complex with a N,N-dimethylformamide ligand captures one CO2 molecule in the presence of triethanolamine (TEOA), giving fac-[Re(I)(bpy)(CO)3{R2N-CH2CH2O-COO}] (bpy = 2,2'-bipyridine, R = CH2CH2OH). This could be a predominant complex in various photocatalytic CO2 reduction reactions using [Re(I)(N^N)(CO)3X](n+) (N^N = diimine ligand; X = monodentate ligand; n = 0, 1) type complexes in the presence of TEOA.Entities:
Year: 2013 PMID: 24156658 DOI: 10.1021/ja409271s
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419