Literature DB >> 24156512

Asymmetric oxidation catalysis by a porphyrin-inspired manganese complex: highly enantioselective sulfoxidation with a wide substrate scope.

Wen Dai1, Jun Li, Bo Chen, Guosong Li, Ying Lv, Lianyue Wang, Shuang Gao.   

Abstract

The first genuinely promising porphyrin-inspired manganese-catalyzed asymmetric sulfoxidation method using hydrogen peroxide has been successfully developed, allowing for rapidly oxidizing (0.5-1.0 h) a wide variety of sulfides in high yields with excellent enantioselectivities (up to >99% ee).

Entities:  

Year:  2013        PMID： 24156512     DOI： 10.1021/ol402612x

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Further Developments and Applications of Oxazoline-Containing Ligands in Asymmetric Catalysis.

Authors:  Robert Connon; Brendan Roche; Balaji V Rokade; Patrick J Guiry
Journal:  Chem Rev       Date:  2021-05-21       Impact factor: 60.622

2.  Dynamic kinetic resolution of allylic sulfoxides by Rh-catalyzed hydrogenation: a combined theoretical and experimental mechanistic study.

Authors:  Peter K Dornan; Kevin G M Kou; K N Houk; Vy M Dong
Journal:  J Am Chem Soc       Date:  2013-12-18       Impact factor: 15.419

Review 3.  Schiff base complex conjugates of bovine serum albumin as artificial metalloenzymes for eco-friendly enantioselective sulfoxidation.

Authors:  Jie Tang; Pengfei Yao; Lina Wang; Hedong Bian; Meiyi Luo; Fuping Huang
Journal:  RSC Adv       Date:  2018-12-05       Impact factor: 4.036

4.  Molybdenum-Catalyzed Enantioselective Sulfoxidation Controlled by a Nonclassical Hydrogen Bond between Coordinated Chiral Imidazolium-Based Dicarboxylate and Peroxido Ligands.

Authors:  Carlos J Carrasco; Francisco Montilla; Agustín Galindo
Journal:  Molecules       Date:  2018-06-30       Impact factor: 4.411
  4 in total

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