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Literature DB >> 24150893

Highly enantioselective decarboxylative Mannich reaction of malonic acid half oxyesters with cyclic trifluoromethyl ketimines: synthesis of β-amino esters and anti-HIV drug DPC 083.

Hai-Na Yuan¹, Shen Li, Jing Nie, Yan Zheng, Jun-An Ma.

Abstract

Entities: Chemical

Keywords: asymmetric catalysis; decarboxylative Mannich reaction; malonic acid half oxyesters; saccharide-derived amino-thioureas; β-amino esters

Mesh：

Substances：

Year: 2013 PMID： 24150893 DOI： 10.1002/chem.201303307

Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236

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8 in total

Review 1. Synthesis and Applications of Carbohydrate-Based Organocatalysts.

Authors: Elżbieta Wojaczyńska; Franz Steppeler; Dominika Iwan; Marie-Christine Scherrmann; Alberto Marra
Journal: Molecules Date: 2021-11-30 Impact factor: 4.411

2. Bioinspired tetraamino-bisthiourea chiral macrocycles in catalyzing decarboxylative Mannich reactions.

Authors: Hao Guo; Yu-Fei Ao; De-Xian Wang; Qi-Qiang Wang
Journal: Beilstein J Org Chem Date: 2022-05-02 Impact factor: 2.544

3. Strategies for the Catalytic Enantioselective Synthesis of α-Trifluoromethyl Amines.

Authors: Chibueze I Onyeagusi; Steven J Malcolmson
Journal: ACS Catal Date: 2020-10-12 Impact factor: 13.084

4. Regioselective decarboxylative addition of malonic acid and its mono(thio)esters to 4-trifluoromethylpyrimidin-2(1H)-ones.

Authors: Sergii V Melnykov; Andrii S Pataman; Yurii V Dmytriv; Svitlana V Shishkina; Mykhailo V Vovk; Volodymyr A Sukach
Journal: Beilstein J Org Chem Date: 2017-12-07 Impact factor: 2.883

5. A bifunctional iminophosphorane squaramide catalyzed enantioselective synthesis of hydroquinazolines via intramolecular aza-Michael reaction to α,β-unsaturated esters.

Authors: Guanglong Su; Connor J Thomson; Ken Yamazaki; Daniel Rozsar; Kirsten E Christensen; Trevor A Hamlin; Darren J Dixon
Journal: Chem Sci Date: 2021-03-18 Impact factor: 9.825

Highly enantioselective decarboxylative Mannich reaction of malonic acid half oxyesters with cyclic trifluoromethyl ketimines: synthesis of β-amino esters and anti-HIV drug DPC 083.

Review 1. Synthesis and Applications of Carbohydrate-Based Organocatalysts.

2. Bioinspired tetraamino-bisthiourea chiral macrocycles in catalyzing decarboxylative Mannich reactions.

3. Strategies for the Catalytic Enantioselective Synthesis of α-Trifluoromethyl Amines.

4. Regioselective decarboxylative addition of malonic acid and its mono(thio)esters to 4-trifluoromethylpyrimidin-2(1H)-ones.

5. A bifunctional iminophosphorane squaramide catalyzed enantioselective synthesis of hydroquinazolines via intramolecular aza-Michael reaction to α,β-unsaturated esters.

6. Organocatalytic asymmetric nitroso aldol reaction of α-substituted malonamates.

7. Efficient and practical synthesis of monoalkyl oxalates under green conditions.

Review 8. Synthesis of 3,4-Dihydropyrimidin(thio)one Containing Scaffold: Biginelli-like Reactions.