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Literature DB >> 24150794

Synthesis of terminal uranium(IV) disulfido and diselenido compounds by activation of elemental sulfur and selenium.

Ellen M Matson¹, Mitchell D Goshert, John J Kiernicki, Brian S Newell, Phillip E Fanwick, Matthew P Shores, Justin R Walensky, Suzanne C Bart.

Abstract

Rare stakes: Terminal uranium(IV) disulfido and diselenido compounds, Tp*2U(E2) (E=S, Se), were synthesized by the activation of elemental chalcogens. Structural, spectroscopic, computational and magnetic studies of these species establish their tetravalency and highly polarized U-E bonds.

Entities: Chemical

Keywords: chalcogens; selenium; sulfur; tridentate ligands; uranium

Mesh：

Substances：

Year: 2013 PMID： 24150794 DOI： 10.1002/chem.201303095

Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236

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Cited

3 in total

1. Reactivity of uranium(iii) with H₂E (E = S, Se, Te): synthesis of a series of mononuclear and dinuclear uranium(iv) hydrochalcogenido complexes.

Authors: Sebastian M Franke; Michael W Rosenzweig; Frank W Heinemann; Karsten Meyer
Journal: Chem Sci Date: 2014-09-29 Impact factor: 9.825

2. Synthesis and reactivity of a terminal uranium(iv) sulfide supported by siloxide ligands.

Authors: Julie Andrez; Jacques Pécaut; Rosario Scopelliti; Christos E Kefalidis; Laurent Maron; Michael W Rosenzweig; Karsten Meyer; Marinella Mazzanti
Journal: Chem Sci Date: 2016-05-10 Impact factor: 9.825

3. Tris-{hydridotris(1-pyrazolyl)borato}actinide Complexes: Synthesis, Spectroscopy, Crystal Structure, Bonding Properties and Magnetic Behaviour.

Authors: Christos Apostolidis; Attila Kovács; Olaf Walter; Eric Colineau; Jean-Christophe Griveau; Alfred Morgenstern; Jean Rebizant; Roberto Caciuffo; Petra J Panak; Thomas Rabung; Bernd Schimmelpfennig; Mauro Perfetti
Journal: Chemistry Date: 2020-07-29 Impact factor: 5.236

3 in total

Synthesis of terminal uranium(IV) disulfido and diselenido compounds by activation of elemental sulfur and selenium.

1. Reactivity of uranium(iii) with H2E (E = S, Se, Te): synthesis of a series of mononuclear and dinuclear uranium(iv) hydrochalcogenido complexes.

2. Synthesis and reactivity of a terminal uranium(iv) sulfide supported by siloxide ligands.

3. Tris-{hydridotris(1-pyrazolyl)borato}actinide Complexes: Synthesis, Spectroscopy, Crystal Structure, Bonding Properties and Magnetic Behaviour.

1. Reactivity of uranium(iii) with H₂E (E = S, Se, Te): synthesis of a series of mononuclear and dinuclear uranium(iv) hydrochalcogenido complexes.