Literature DB >> 24150033

The first bismuth-NHC complexes.

Antonino Aprile1, Robert Corbo, Kel Vin Tan, David J D Wilson, Jason L Dutton.   

Abstract

The synthesis, isolation and crystallographic characterization of the first N-heterocyclic carbene adducts of bismuth is reported, by direct reaction of the Dipp2NHC (Dipp = 2,6-diisopropylphenyl) or (i)Pr2(Me2)NHC with BiCl3. This represents the last non-radioactive element from groups 13-17 for which an NHC-element fragment remained unreported.

Entities:  

Year:  2013        PMID： 24150033     DOI： 10.1039/c3dt52715h

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  2 in total

1.  Indirect Access to Carbene Adducts of Bismuth- and Antimony-Substituted Phosphaketene and Their Unusual Thermal Transformation to Dipnictines and [(NHC)2OCP][OCP].

Authors:  Jacob E Walley; Levi S Warring; Erik Kertész; Guocang Wang; Diane A Dickie; Zoltán Benkő; Robert J Gilliard
Journal:  Inorg Chem       Date:  2021-03-09       Impact factor: 5.165

2.  Isolation of Cyclic(Alkyl)(Amino) Carbene-Bismuthinidene Mediated by a Beryllium(0) Complex.

Authors:  Guocang Wang; Lucas A Freeman; Diane A Dickie; Réka Mokrai; Zoltán Benkő; Robert J Gilliard
Journal:  Chemistry       Date:  2019-02-27       Impact factor: 5.236
  2 in total

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