Literature DB >> 24144014

Oxidant-free conversion of primary amines to nitriles.

Kuei-Nin T Tseng1, Andrew M Rizzi, Nathaniel K Szymczak.   

Abstract

An amide-derived NNN-Ru(II) hydride complex catalyzes oxidant-free, acceptorless, and chemoselective dehydrogenation of primary and secondary amines to the corresponding nitriles and imines with liberation of dihydrogen. The catalyst system tolerates oxidizable functionality and is selective for the dehydrogenation of primary amines (-CH2NH2) in the presence of amines without α-CH hydrogens.

Entities:  

Mesh：

Substances：

Year:  2013        PMID： 24144014     DOI： 10.1021/ja409223a

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  6 in total

1.  Synthesis of nitriles via palladium-catalyzed water shuffling from amides to acetonitrile.

Authors:  Wandi Zhang; Christopher W Haskins; Yang Yang; Mingji Dai
Journal:  Org Biomol Chem       Date:  2014-12-07       Impact factor: 3.876

2.  Stereoretentive Deuteration of α-Chiral Amines with D2O.

Authors:  Lillian V A Hale; Nathaniel K Szymczak
Journal:  J Am Chem Soc       Date:  2016-10-06       Impact factor: 15.419

3.  Nitrogen-coordinated cobalt nanocrystals for oxidative dehydrogenation and hydrogenation of N-heterocycles.

Authors:  Yue Wu; Zheng Chen; Weng-Chon Cheong; Chao Zhang; Lirong Zheng; Wensheng Yan; Rong Yu; Chen Chen; Yadong Li
Journal:  Chem Sci       Date:  2019-04-23       Impact factor: 9.825

4.  Efficient photocatalytic hydrogen peroxide generation coupled with selective benzylamine oxidation over defective ZrS3 nanobelts.

Authors:  Zhangliu Tian; Cheng Han; Yao Zhao; Wenrui Dai; Xu Lian; Yanan Wang; Yue Zheng; Yi Shi; Xuan Pan; Zhichao Huang; Hexing Li; Wei Chen
Journal:  Nat Commun       Date:  2021-04-01       Impact factor: 14.919

5.  Non-metal-mediated N-oxyl radical (TEMPO)-induced acceptorless dehydrogenation of N-heterocycles via electrocatalysis.

Authors:  Huiqing Hou; Xinhua Ma; Yaling Ye; Mei Wu; Sunjie Shi; Wenhe Zheng; Mei Lin; Weiming Sun; Fang Ke
Journal:  RSC Adv       Date:  2022-02-16       Impact factor: 3.361

6.  Acceptorless dehydrogenation and hydrogenation of N- and O-containing compounds on Pd3Au1(111) facets.

Authors:  Xinjiang Cui; Zhangjun Huang; Antoine P van Muyden; Zhaofu Fei; Tao Wang; Paul J Dyson
Journal:  Sci Adv       Date:  2020-07-01       Impact factor: 14.136
  6 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.