Literature DB >> 24141427

On the chemical reactions of carbon dioxide isoelectronic molecules CS2 and OCS with 1-butyl-3-methylimidazolium acetate.

M Isabel Cabaço1, Marcel Besnard, Fabián Vaca Chávez, Noël Pinaud, Pedro J Sebastião, João A P Coutinho, Joëlle Mascetti, Yann Danten.   

Abstract

Raman and NMR spectroscopies show that CS2 and OCS react spontaneously with 1-butyl-3-methylimidazolium acetate [C4mim] [Ac] in the liquid phase. The formation of [C4mim] CO2, [C4mim] COS, CH3COS(-) and gaseous CO2 and OCS in both systems demonstrates that the anion plays an unexpected role not observed in the CO2-[C4mim] [Ac] reaction.

Entities:  

Year:  2013        PMID: 24141427     DOI: 10.1039/c3cc46038j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Simple Ion-Gas Mixtures as a Source of Key Molecules Relevant to Prebiotic Chemistry.

Authors:  Samuel Paula; Liam S Goulding; Katherine N Robertson; Jason A C Clyburne
Journal:  Molecules       Date:  2021-12-06       Impact factor: 4.411

  1 in total

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