Literature DB >> 24136154

Room temperature switching of a neutral molecular iron(II) complex.

Bernhard Schäfer1, Cyril Rajnák, Ivan Šalitroš, Olaf Fuhr, David Klar, Carolin Schmitz-Antoniak, Eugen Weschke, Heiko Wende, Mario Ruben.   

Abstract

Abrupt room temperature switching (T(c) = 295 K with a 5 K hysteresis) was achieved in a neutral Fe(II) complex based on a 2-(1H-pyrazol-1-yl)-6-(1H-tetrazol-5-yl)pyridine ligand. Structural characterization and spin crossover study (via SQUID magnetometry, photoexcitation and X-ray absorption spectroscopy) in the solid state are described.

Entities:  

Year:  2013        PMID： 24136154     DOI： 10.1039/c3cc46624h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Divergent Coordination Chemistry: Parallel Synthesis of [2×2] Iron(II) Grid-Complex Tauto-Conformers.

Authors:  Bernhard Schäfer; Jean-François Greisch; Isabelle Faus; Tilmann Bodenstein; Ivan Šalitroš; Olaf Fuhr; Karin Fink; Volker Schünemann; Manfred M Kappes; Mario Ruben
Journal:  Angew Chem Int Ed Engl       Date:  2016-07-13       Impact factor: 15.336

2.  2,6-Dicyano-4-pyrone as a Novel and Multifarious Building Block for the Synthesis of 2,6-Bis(hetaryl)-4-pyrones and 2,6-Bis(hetaryl)-4-pyridinols.

Authors:  Dmitrii L Obydennov; Alena E Simbirtseva; Sergey E Piksin; Vyacheslav Y Sosnovskikh
Journal:  ACS Omega       Date:  2020-12-15

3.  Structural Insights into Hysteretic Spin-Crossover in a Set of Iron(II)-2,6-bis(1H-Pyrazol-1-yl)Pyridine) Complexes.

Authors:  Nithin Suryadevara; Asato Mizuno; Lea Spieker; Soma Salamon; Stephan Sleziona; André Maas; Erik Pollmann; Benoît Heinrich; Marika Schleberger; Heiko Wende; Senthil Kumar Kuppusamy; Mario Ruben
Journal:  Chemistry       Date:  2022-01-19       Impact factor: 5.020

4.  105 K Wide Room Temperature Spin Transition Memory Due to a Supramolecular Latch Mechanism.

Authors:  Maksym Seredyuk; Kateryna Znovjyak; Francisco Javier Valverde-Muñoz; Ivan da Silva; M Carmen Muñoz; Yurii S Moroz; José Antonio Real
Journal:  J Am Chem Soc       Date:  2022-07-28       Impact factor: 16.383
  4 in total

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