Literature DB >> 24125572

Aziridine nitrogen inversion by dynamic NMR: activation parameters in a fused bicyclic structure.

Denisse de Loera1, Fang Liu, K N Houk, Miguel A Garcia-Garibay.   

Abstract

The nitrogen inversion of a N-phenyl aziridine fused to a succinimide ring is influenced by the presence of a phenyl ring in the succinimide moiety. The endo invertomer is favored, showing an unsymmetrical equilibrium in variable (1)H NMR studies.

Entities:  

Year:  2013        PMID: 24125572     DOI: 10.1021/jo4022315

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  1 in total

1.  Tunable Aziridinium Ylide Reactivity: Non-covalent Interactions Enable Divergent Product Outcomes.

Authors:  Kate A Nicastri; Soren Zappia; Jared C Pratt; Julia M Duncan; Ilia A Guzei; Israel Fernández; Jennifer M Schomaker
Journal:  ACS Catal       Date:  2022-01-11       Impact factor: 13.084

  1 in total

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