Literature DB >> 24125480

Platinum-catalyzed C-H arylation of simple arenes.

Anna M Wagner1, Amanda J Hickman, Melanie S Sanford.   

Abstract

This report describes the Na2PtCl4 catalyzed C-H arylation of arene substrates with diaryliodonium salts. The site selectivity of these reactions is predominantly controlled by steric factors. Remarkably, Na2PtCl4-catalyzed naphthalene arylation proceeds with opposite site selectivity compared to that obtained with Na2PdCl4 as the catalyst. Preliminary mechanistic studies provide evidence for a Pt(II)/Pt(IV) catalytic cycle involving rate-limiting C-C bond-forming reductive elimination.

Entities:  

Year:  2013        PMID： 24125480     DOI： 10.1021/ja408112j

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  12 in total

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Authors:  David E Stephens; Oleg V Larionov
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Authors:  David E Stephens; Johant Lakey-Beitia; Abdurrahman C Atesin; Tülay A Ateşin; Gabriel Chavez; Hadi D Arman; Oleg V Larionov
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7.  meta-Selective C-H Borylation of Benzylamine-, Phenethylamine-, and Phenylpropylamine-Derived Amides Enabled by a Single Anionic Ligand.

Authors:  Holly J Davis; Georgi R Genov; Robert J Phipps
Journal:  Angew Chem Int Ed Engl       Date:  2017-09-19       Impact factor: 15.336

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9.  Palladium-catalyzed direct β-arylation of ketones with diaryliodonium salts: a stoichiometric heavy metal-free and user-friendly approach.

Authors:  Zhongxing Huang; Quynh P Sam; Guangbin Dong
Journal:  Chem Sci       Date:  2015-06-17       Impact factor: 9.825

10.  Pd(ii)-catalyzed remote regiodivergent ortho- and meta-C-H functionalizations of phenylethylamines.

Authors:  Shangda Li; Huafang Ji; Lei Cai; Gang Li
Journal:  Chem Sci       Date:  2015-06-25       Impact factor: 9.825
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